A synthetic approach that improves absorber layers in perovskite solar cells could help them achieve their full potential and draw closer to the performance of leading gallium arsenide devices.

Solar cells that rely on perovskite thin films to capture sunlight are the fastest growing photovoltaic technology. Cheaper and easier to manufacture and incorporate into devices than conventional semiconductors, lead halide perovskites also effectively absorb visible light and display long charge carrier diffusion lengths - an indicator of their ability to maintain light-induced electrons and holes separation and facilitate charge transport.

Performance of solar cells hinges on absorber materials with a high-quality crystal structure and a narrow bandgap to maximize sunlight harvesting. This optimal bandgap range spans energies of 1.1 to 1.4 eV, which corresponds to near-infrared wavelengths.

Absorber layers containing polycrystalline lead halide perovskites have provided high-efficiency solar cells. Their performance, however, has been affected by considerable structural disorder and defects. Formamidinium lead triiodide features the smallest bandgap to date, but this bandgap exceeds the optimal range for single-junction devices. One way to reduce the bandgap of perovskites involves forming lead-tin alloys in the absorber, but this introduces crystal defects and instability.

Now, a team from KAUST has developed an approach using a microns-thick absorber layer consisting of perovskite single crystals to minimize the bandgap. The crystals contain a mixture of methylammonium and formamidinium organic cations.

The researchers incorporated the mixed-cation perovskite into unconventional inverted p-i-n solar cells, in which the absorber is sandwiched between an electron transport top layer and a hole transport bottom layer. The resulting solar cells exhibited an efficiency of 22.8 percent, surpassing the best-performing devices using single-crystal methylammonium lead triiodide.

"We had known that mixed-cation single-crystal absorbers could outperform single-cation absorbers due to their lower bandgap and superior optoelectronic qualities. However, this had not been realized before because of challenges in crystal growth and device integration," says Abdullah Alsalloum, a Ph.D. student in Osman Bakr's group.

The external quantum efficiency of the mixed-cation perovskite film, which measures its effectiveness when converting incoming light into charge carriers, shifted toward near-infrared wavelengths from that of polycrystalline formamidinium lead triiodide, consistent with its smaller bandgap. "By utilizing a thicker single-crystal absorber layer, we expanded the absorption range of the film so that it's very close to the optimal range," Alsalloum says.

The team is working on enhancing device performance and stability to get even closer to the top-performing gallium arsenide solar cells. "Future studies include optimizing device interfaces and exploring more favorable device structures," Alsalloum adds.

Research paper

Related Links
King Abdullah University Of Science and Technology
All About Solar Energy at SolarDaily.com

Tweet

Thanks for being here; We need your help. The Space Media Network continues to grow but revenues have never been harder to maintain. With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords. Our news coverage takes time and effort to publish 365 days a year. If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.
SpaceMediaNetwork Contributor $5 Billed Once credit card or paypal		SpaceMediaNetwork Monthly Supporter $5 Billed Monthly paypal only

'Molecular glue' makes perovskite solar cells dramatically more reliable over time
Providence RI (SPX) May 07, 2021
A research team from Brown University has made a major step toward improving the long-term reliability of perovskite solar cells, an emerging clean energy technology. In a study to be published on Friday, May 7 in the journal Science, the team demonstrates a "molecular glue" that keeps a key interface inside cells from degrading. The treatment dramatically increases cells' stability and reliability over time, while also improving the efficiency with which they convert sunlight into electricity. "T ... read more