Researchers at the University of Calgary and University of Ottawa have provided deeper insights to CO2 capture by "seeing" the exact sites where CO2 is held in a capture material. Their discovery, published in prestigious journal Science, will allow scientists to design better materials to capture more CO2.

The findings can be likened to learning about a better fit between a baseball glove and a ball in order to improve performance. Different gloves fit different size of balls better and it's easier to catch a ball with a glove that is moulded to it. In the case of CO2 capture, think of the ball as the CO2 and the glove as the material that houses the CO2.

"We have pinpointed where the CO2 molecule is held by direct experimental visualization (X-ray crystallography) and, through computer modeling, we can see how every 'finger' contributes to holding the CO2 in place," says co-author Dr. George Shimizu, a chemistry professor in the Faculty of Science at the University of Calgary whose research was funded by the University of Calgary's Institute for Sustainable Energy, Environment and Economy and NSERC.

What's also significant about this discovery is the exceptional correlation between experiment and computer simulation. Computer simulations can now be more confidently applied to predict the CO2 capture ability of materials on the computer before they are made in the laboratory.

"The detailed computational analysis of how CO2 is captured in this material provides new directions for designing improved materials," says Dr. Tom Woo, an associate professor in chemistry and Canada Research Chair at the University of Ottawa, who is a co-author of the work along with his graduate student Peter Boyd.

This research may be used for a variety of applications. "We could ultimately see this process helping to mitigate greenhouse gas emissions on the top of coal burning flue stacks or it could be used to help remove CO2 from unconventional natural gas reservoirs," says Dr. Ramanathan Vaidhyanathan, the paper's first author and research associate at the University of Calgary.

Current methods of CO2 capture take place by bubbling CO2 through a liquid solution which strongly binds to the CO2, a process called amine scrubbing. The major downside of this technology is that to recycle to the absorbing solution and release the CO2, heating to over 100 C is required. Most estimates say to capture CO2 from a coal-fired power plant by this technique would cost about one-quarter of the plant's energy production.

The article, entitled Direct observation and quantification of CO2 binding within an amine-functionalized nanoporous solid, is published in Science and written by Ramanathan Vaidhyanathan, Simon S. Iremonger and George K. H. Shimizu from the University of Calgary and Peter G. Boyd, Saman Alavi, Tom K. Woo from the University of Ottawa.

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