Cool some water below 32F and it freezes into solid ice; heat it above 212F and it boils, becoming gaseous steam.

Pluto's surface materials have phase changes too. Nitrogen, methane, and carbon monoxide are detected as solid ices on Pluto's surface, and will be mapped by the instruments aboard New Horizons. But they cannot melt and become liquid, because Pluto's surface pressure is too low. (On Earth, we see the same behavior in frozen carbon dioxide (dry ice), which transforms directly from ice to gas [or "sublimates"] because the pressure at Earth's surface is too low for liquid carbon dioxide to exist.)

Pluto's ices sublimate directly to gas in the same way. Sunshine is weak on Pluto, about a factor of a thousand weaker than on Earth, but it still provides enough heat to cause a little bit of Pluto's surface ices to sublimate into the atmosphere when the Sun shines.

Nitrogen is the most volatile of the three known Plutonian ices, followed by carbon monoxide, and then methane. When a mixture of the three ices sublimates, the nitrogen is most readily lost, while the methane tends to linger behind. The surface composition gradually changes as a result of solar-powered sublimation.

Another, more exotic kind of phase change affects Pluto's surface ices. When nitrogen ice is cooled below -396F, its molecules move around and reorganize themselves from a hexagonal crystal structure into a cubic crystal structure.

On warming back up, they revert back to the hexagonal arrangement. Although they are unfamiliar in room temperature materials, this type of phase change between two different solid phases is common among volatile ices.

Methane ice has such a transition at -423F, and carbon monoxide has one at -350F. Ethane ice, also present on Pluto's surface, has two phase transitions, one at -298.0F and one at -298.2F.

These exotic volatile ices may be the construction materials for what are expected to be correspondingly exotic landforms on Pluto. These will be imaged in exquisite detail by the New Horizons LORRI and MVIC cameras, and our LEISA instrument will reveal what ices make up these landforms.