Perovskite solar cells are attracting attention as the next-generation solar battery material thanks to their low processing cost and excellent photovoltaic quality. However, it is difficult to commercialize them because their key material - perovskite - is vulnerable to light and moisture.

Recently, a POSTECH research team has developed an organic spacer molecular additive that can improve both the photoelectric efficiency and stability of perovskite.

A POSTECH research team led by Professor Kilwon Cho and Ph.D. candidate Sungwon Song of the Department of Chemical Engineering has succeeded in fabricating perovskite solar cells that are highly efficient and stable by drastically reducing the concentration of internal defects in the crystals as well as increasing the moisture resistance of perovskite by introducing a new organic spacer molecule additive in the perovskite crystal. The study was published as a cover paper in the latest issue of Advanced Energy Materials, one of the most authoritative journals in the field of energy.

By adding organic spacer ions to solve the problem, the research team developed a hybrid perovskite photovoltaic layer where two- and three-dimensional perovskite coexist. Organic spacers create two-dimensional perovskite structures on the surface of 3D perovskite crystals. These structures act as stabilizing layer that increases resistance to moisture due to its property of repelling water.

In addition, it was discovered for the first time that this newly introduced organic spacer minimizes mechanical stress of the two- and three-dimensional perovskite crystal interfaces, thus promoting the nuclear production and growth of the 3D perovskite crystal. As a result, the internal defects of the photoreactive layer - the 3D perovskite crystals - have been dramatically reduced.

The solar cells developed by the research team achieved 21.3 % efficiency and secured moisture stability to maintain more than 80% of their initial efficiency even after 500 hours under 60% of relative humidity conditions.

"This study has presented a new perspective on organic spacer molecular design for the realization of high performing and stable perovskite solar cells," remarked Professor Kilwon Cho who led the study. He added, "It is anticipated to be a source technology that can contribute to the commercialization of perovskite solar cell technology."

Research paper

Related Links
Pohang University of Science and Technology
All About Solar Energy at SolarDaily.com

Tweet

Thanks for being here; We need your help. The Space Media Network continues to grow but revenues have never been harder to maintain. With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords. Our news coverage takes time and effort to publish 365 days a year. If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.
SpaceMediaNetwork Contributor $5 Billed Once credit card or paypal		SpaceMediaNetwork Monthly Supporter $5 Billed Monthly paypal only

Trina Solar and Tongwei join forces to further upgrade the 210 integrated industrial chain
Zurich, Switzerland (SPX) Nov 20, 2020
Trina Solar reports it's agreement with Tongwei Co., Ltd. has reached a new level, with three investments and a long term procurement cooperation framework agreement now in place. Gao Jifan, Chairman of Trina Solar, said that the two leading companies focused on 210 products and cooperated to make the 210 industrial ecosystem stronger and bigger. Joint ventures and cooperation among strong players, who complement each other, have bigger advantages than simple vertical integrations within themselve ... read more