NATO member Poland on Tuesday suggested the alliance deploy an armed "peace mission" in Ukraine to provide humanitarian aid in the face of Moscow's devastating onslaught.

"We support peace efforts, we call on Russia, on President (Vladimir) Putin to withdraw its forces, but we have no plans of deploying NATO troops on the ground in Ukraine," Stoltenberg told journalists after a meeting of NATO defence ministers.

NATO has already rebuffed pleas from non-member state Ukraine to intervene in the conflict, including by imposing a no-fly zone to help halt Russian bombings.

The US-led alliance says its direct involvement could spark a confrontation with Russia that may spill over into nuclear war.

NATO allies have instead been sending weapons to help Ukrainian forces to defend their country, especially vital portable anti-tank and anti-aircraft missile systems.

Moscow has warned that any deliveries are legitimate targets for its military to strike.

"Ministers addressed this today, they reinforced the message of the importance of providing support with equipment, advanced equipment, air defence systems, anti-tank weapons and many other types of support," Stoltenberg said.

"But no NATO deployment of air or ground capabilities in Ukraine."

- Defence 'reset' -

While the 30-nation alliance has refused to intervene directly in the war in Ukraine, it has already temporarily shifted tens of thousands of troops closer to prevent any spillover from the conflict.

Stoltenberg said defence ministers had now tasked military commanders to come up with plans to "reset our collective defence and deterrence for the longer term".

"On land, our new posture should include substantially more forces in the eastern part of the alliance, at higher readiness with more pre-positioned equipment and supplies," he said.

"In the air: more allied air power and strengthened integrated air and missile defence. At sea: carrier strike groups, submarines and significant numbers of combat ships on a persistent basis."

NATO leaders are set to hold an emergency summit next week in Brussels on the Ukraine war and their response to Russia's assault.

Ukraine and Russia are currently locked in negotiations that Kyiv hopes will lead to a ceasefire and peace deal.

The Kremlin is pushing for Ukraine to drop any ambitions of joining NATO, while Kyiv insists it needs concrete security guarantees that prevent any future attack.

Stoltenberg said it was up to the Ukrainians "to decide whether they aspire for NATO membership or not".

He called on Russia to engage in peace talks in "good faith" but warned there were not yet any signs on the ground that Moscow was looking to pull back.

"What Ukraine can achieve around the negotiating table is very closely linked to the situation on the ground and therefore the support we give to them to stand up against and to resist the Russian invasion also helps," Stoltenberg said.